File name: Pandora177s1_WestportCT_20240919_L2Fit_fout2c5d20230401p1-8.txt File generation date: 20240920T055440.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v5d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20240919_L1_smca1c5d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20240919 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.0996 305.2405 305.3814 305.5223 305.6632 305.8041 305.9450 306.0858 306.2267 306.3675 306.5084 306.6492 306.7900 306.9308 307.0716 307.2123 307.3531 307.4939 307.6346 307.7753 307.9161 308.0568 308.1975 308.3382 308.4788 308.6195 308.7602 308.9008 309.0414 309.1821 309.3227 309.4633 309.6039 309.7444 309.8850 310.0256 310.1661 310.3067 310.4472 310.5877 310.7282 310.8687 311.0092 311.1496 311.2901 311.4305 311.5710 311.7114 311.8518 311.9922 312.1326 312.2730 312.4134 312.5537 312.6941 312.8344 312.9747 313.1151 313.2554 313.3957 313.5359 313.6762 313.8165 313.9567 314.0970 314.2372 314.3774 314.5176 314.6578 314.7980 314.9381 315.0783 315.2184 315.3586 315.4987 315.6388 315.7789 315.9190 316.0591 316.1992 316.3392 316.4793 316.6193 316.7593 316.8993 317.0393 317.1793 317.3193 317.4593 317.5992 317.7392 317.8791 318.0190 318.1589 318.2988 318.4387 318.5786 318.7185 318.8583 318.9982 319.1380 319.2778 319.4176 319.5574 319.6972 319.8370 319.9768 320.1165 320.2562 320.3960 320.5357 320.6754 320.8151 320.9548 321.0945 321.2341 321.3738 321.5134 321.6530 321.7926 321.9322 322.0718 322.2114 322.3510 322.4905 322.6301 322.7696 322.9091 323.0487 323.1882 323.3276 323.4671 323.6066 323.7460 323.8855 324.0249 324.1643 324.3038 324.4431 324.5825 324.7219 324.8613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240919T134229.3Z 9028.571172 318 1 2.76 2 57.64 121.45 104.10 293.02 0.00 1 0.00 1 0 25 1.701e-02 1.232e-02 2.747e-03 1.321e-03 2.362725e-01 6.997980e-04 2.839916e-03 -6.000000e+00 1.016956e-02 228.70 -2.00 3.51 -2.00 316.26 0.00e+00 1.018556e-03 7.926507e-05 2.666828e-04 -6.000000e+00 4.545776e-04 287.20 -2.00 20.00 -2.00 315.50 0.00e+00 1.862 0.000 302.00 328.00 3 1.7056e+00 1.8177e-03 2.2190e-02 -6.0000e+00 2.5274e-02 2.0767e-02 2.0243e-03 1.2039e-02 -6.0000e+00 2.7291e-02 -8.6108e-04 1.1709e-03 5.8683e-03 -6.0000e+00 1.6288e-02 -6.7350e-03 5.4683e-04 1.6740e-03 -6.0000e+00 6.9785e-03 1.1337e-02 3.4808e-04 4.0263e-05 2.0591e-05 -6.0000e+00 5.0065e-04 1.3100e-02 0.0000e+00 12 9 9 12 9 1 93.54 23.20 0.28 0.01310 0.01572 23 98 1 5 0 113.880 26.51 20.00 23.20 27.46 26.2 1036.74 2117 579 -450 -4771 -4294 -2776 -556 347 -1694 -2977 -5871 -2833 -2255 225 617 477 902 1905 1980 1784 505 1092 1455 1691 2160 469 -816 -1128 -981 -36 870 1579 241 -3879 -6345 -4656 -3402 -1222 -200 -260 -529 140 485 462 1267 161 -156 -226 -507 99 855 926 1155 1023 618 1372 437 -371 -77 -22 1506 2536 3139 1809 18 -1302 -1575 -337 1641 1326 1099 1421 877 1435 -455 -1727 -3060 -3373 -2116 -2492 -2246 -2712 -2726 -1452 -137 435 1418 1265 1544 1411 330 -1030 -1734 -599 -822 -117 793 1467 667 -600 -1328 -2224 -908 -464 -1679 -1663 -1001 -696 1016 1552 1607 1116 602 -136 -438 -507 -207 185 1074 562 812 782 1252 763 756 -620 -627 569 -136 -152 -1034 -1174 -445 47 241 138 747 802 611 -343 -615 -1727 389 114 -88 -903 -740 -461 -98 68 -364 -660 -1344 -665 -593 61 185 153 300 651 700 650 188 404 549 671 896 185 -342 -448 -371 -14 344 673 101 -1672 -2688 -1965 -1587 -663 -117 -160 -351 96 337 323 878 112 -106 -150 -333 66 598 690 848 779 485 1090 353 -298 -61 -18 1246 2108 2779 1674 16 -1110 -1341 -286 1412 1270 1065 1405 858 1408 -419 -1540 -2544 -2778 -1852 -2312 -2181 -2868 -2894 -1610 -160 512 1734 1572 1881 1638 375 -1139 -1805 -620 -917 -136 955 1895 851 -749 -1624 -2697 -1078 -549 -2156 -2145 -1339 -970 1405 2257 2406 1659 853 -188 -591 -660 -273 244 1506 793 1155 1092 1760 1033 1024 -808 -794 733 -179 -213 -1514 -1675 -650 71 371 221 1218 1323 1005 -556 -961 -2651 SS 20240919T135151.2Z 9028.577676 321 1 48.77 2 56.15 123.61 105.61 294.70 0.00 1 0.00 1 0 17 1.740e-02 1.170e-02 6.687e-04 2.491e-04 2.273277e-01 1.306076e-04 2.724924e-03 -6.000000e+00 1.040650e-02 228.69 -2.00 3.51 -2.00 317.04 0.00e+00 1.161154e-03 1.777934e-05 3.723624e-04 -6.000000e+00 4.651737e-04 287.20 -2.00 20.00 -2.00 316.25 0.00e+00 1.790 0.000 302.00 328.00 3 9.5547e-01 3.4316e-04 2.1346e-02 -6.0000e+00 2.5862e-02 1.5391e-02 3.8461e-04 1.1600e-02 -6.0000e+00 2.7927e-02 -1.7097e-04 2.2603e-04 5.6779e-03 -6.0000e+00 1.6668e-02 -7.9697e-03 1.0894e-04 1.6451e-03 -6.0000e+00 7.1409e-03 2.6221e-02 3.9182e-04 7.6918e-06 1.8694e-05 -6.0000e+00 5.1233e-04 1.3213e-02 0.0000e+00 12 8 8 10 0 0 98.84 23.19 0.32 0.01321 0.01616 1095 252 1 5 0 44.530 26.51 20.01 23.19 28.57 26.4 1045.85 2031 361 -421 -4362 -4077 -4436 -1628 -468 -1936 -4527 -5874 -3523 -2036 330 394 257 309 1655 1735 2236 923 862 1826 1622 1649 262 -787 -1172 -957 -321 1318 1675 384 -3927 -5957 -4865 -3664 -989 -272 -697 -524 -117 330 232 1040 360 -23 -515 -925 160 1012 1083 1107 1027 537 1353 333 -227 -299 200 1395 2361 2898 2107 -38 -1413 -1573 -697 1800 1279 1078 1483 1097 1219 -330 -1611 -2873 -3304 -1995 -2349 -2336 -2598 -2852 -1563 -294 455 1331 1303 1645 1290 338 -1049 -1711 -698 -713 -176 772 1392 512 -565 -1578 -2124 -924 -571 -1723 -1758 -1052 -709 883 1447 1454 992 539 -172 -600 -399 -76 196 968 460 760 703 1186 695 795 -805 -569 506 1 -202 -951 -1154 -444 56 296 156 791 779 526 -134 -564 -1588 274 52 -60 -601 -512 -547 -211 -67 -303 -739 -973 -601 -385 70 93 65 81 443 480 633 267 249 534 500 533 87 -255 -361 -280 -93 400 548 134 -1408 -2089 -1709 -1422 -444 -129 -374 -301 -69 199 141 626 216 -13 -296 -527 92 608 693 745 716 386 982 246 -166 -217 146 1058 1911 2497 1884 -34 -1166 -1216 -540 1491 1181 977 1370 1002 1156 -292 -1302 -2162 -2463 -1579 -2091 -2308 -2555 -2977 -1704 -338 555 1684 1673 2071 1552 378 -1078 -1655 -733 -736 -199 956 1850 652 -761 -1988 -2513 -1073 -698 -2278 -2265 -1404 -986 1277 2196 2272 1538 794 -236 -830 -531 -103 279 1350 677 1128 1023 1659 936 1104 -1078 -739 669 1 -281 -1379 -1707 -673 88 491 271 1398 1295 872 -235 -958 -2647 SS 20240919T140139.5Z 9028.584485 324 1 48.89 2 54.64 125.95 107.18 296.51 0.00 1 0.00 1 0 17 1.706e-02 1.175e-02 6.120e-04 2.405e-04 2.193019e-01 1.262915e-04 2.649488e-03 -6.000000e+00 1.020179e-02 228.69 -2.00 3.51 -2.00 316.92 0.00e+00 1.069479e-03 1.664646e-05 3.707924e-04 -6.000000e+00 4.560368e-04 287.20 -2.00 20.00 -2.00 316.13 0.00e+00 1.723 0.000 302.00 328.00 3 9.4591e-01 3.3079e-04 2.0567e-02 -6.0000e+00 2.5354e-02 1.5569e-02 3.6994e-04 1.1197e-02 -6.0000e+00 2.7378e-02 1.6404e-05 2.1710e-04 5.4724e-03 -6.0000e+00 1.6340e-02 -7.8199e-03 1.0413e-04 1.5646e-03 -6.0000e+00 7.0002e-03 2.8667e-02 3.7442e-04 7.4521e-06 1.8128e-05 -6.0000e+00 5.0228e-04 1.3521e-02 0.0000e+00 12 8 8 10 0 0 87.54 23.19 0.32 0.01352 0.01633 1231 283 1 5 0 39.610 26.51 20.01 23.19 29.29 26.3 1049.35 1880 491 -235 -4014 -4172 -3607 -1502 -184 -2025 -4540 -5637 -3489 -1782 171 550 126 325 1730 1701 2360 904 793 1592 1834 1688 577 -805 -1088 -990 -412 1333 1642 423 -3860 -5780 -4815 -3604 -968 -327 -760 -605 -2 363 343 985 330 -108 -581 -1005 28 967 992 1126 964 613 1262 337 -252 -332 192 1432 2413 2966 2155 -90 -1365 -1603 -760 1779 1305 1034 1436 1192 1240 -339 -1626 -2873 -3276 -1945 -2354 -2293 -2600 -2827 -1507 -273 434 1337 1320 1648 1221 320 -1034 -1707 -685 -665 -197 741 1345 437 -611 -1627 -2176 -955 -572 -1696 -1755 -999 -642 966 1524 1531 1056 583 -119 -539 -389 -93 187 968 476 695 708 1116 658 778 -852 -602 487 3 -232 -965 -1155 -423 25 282 127 748 725 523 -131 -627 -1597 274 77 -36 -592 -562 -473 -208 -28 -339 -793 -994 -634 -357 38 137 34 90 485 493 699 274 240 489 590 570 199 -272 -349 -302 -124 419 556 152 -1426 -2084 -1741 -1440 -447 -160 -419 -358 -1 225 213 608 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