File name: Pandora177s1_WestportCT_20241003_L2Fit_fout2c5d20230401p1-8.txt File generation date: 20241004T065027.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v5d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20241003_L1_smca1c5d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20241003 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.0996 305.2405 305.3814 305.5223 305.6632 305.8041 305.9450 306.0858 306.2267 306.3675 306.5084 306.6492 306.7900 306.9308 307.0716 307.2123 307.3531 307.4939 307.6346 307.7753 307.9161 308.0568 308.1975 308.3382 308.4788 308.6195 308.7602 308.9008 309.0414 309.1821 309.3227 309.4633 309.6039 309.7444 309.8850 310.0256 310.1661 310.3067 310.4472 310.5877 310.7282 310.8687 311.0092 311.1496 311.2901 311.4305 311.5710 311.7114 311.8518 311.9922 312.1326 312.2730 312.4134 312.5537 312.6941 312.8344 312.9747 313.1151 313.2554 313.3957 313.5359 313.6762 313.8165 313.9567 314.0970 314.2372 314.3774 314.5176 314.6578 314.7980 314.9381 315.0783 315.2184 315.3586 315.4987 315.6388 315.7789 315.9190 316.0591 316.1992 316.3392 316.4793 316.6193 316.7593 316.8993 317.0393 317.1793 317.3193 317.4593 317.5992 317.7392 317.8791 318.0190 318.1589 318.2988 318.4387 318.5786 318.7185 318.8583 318.9982 319.1380 319.2778 319.4176 319.5574 319.6972 319.8370 319.9768 320.1165 320.2562 320.3960 320.5357 320.6754 320.8151 320.9548 321.0945 321.2341 321.3738 321.5134 321.6530 321.7926 321.9322 322.0718 322.2114 322.3510 322.4905 322.6301 322.7696 322.9091 323.0487 323.1882 323.3276 323.4671 323.6066 323.7460 323.8855 324.0249 324.1643 324.3038 324.4431 324.5825 324.7219 324.8613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241003T125053.9Z 9042.535346 95 1 14.96 2 69.46 115.65 78.21 113.33 0.00 1 0.00 1 0 17 3.442e-02 1.197e-02 1.367e-02 1.907e-03 3.478836e-01 9.939749e-04 4.289157e-03 -6.000000e+00 2.048846e-02 227.15 -2.00 3.51 -2.00 318.72 0.00e+00 1.526506e-03 2.191795e-04 1.403411e-03 -6.000000e+00 9.138019e-04 285.51 -2.00 20.00 -2.00 317.97 0.00e+00 2.821 0.000 302.00 328.00 3 2.6744e+00 2.7113e-03 3.3648e-02 -6.0000e+00 5.0764e-02 -2.7168e-03 3.1096e-03 1.8919e-02 -6.0000e+00 5.4874e-02 6.7490e-03 2.1401e-03 9.2940e-03 -6.0000e+00 3.2757e-02 -1.0431e-02 1.1200e-03 2.5979e-03 -6.0000e+00 1.4073e-02 1.4445e-03 1.9512e-04 5.9014e-05 2.9666e-05 -6.0000e+00 1.0128e-03 5.7553e-03 0.0000e+00 12 9 9 12 1 1 99.51 23.25 0.36 0.00576 0.00722 33 26 1 5 0 439.950 26.62 20.00 23.25 23.31 26.0 1008.79 -5121 -4871 170 -7666 -8614 -14822 -4971 -14014 -13318 -13096 -12789 -4444 -6520 -1559 -1005 1806 -787 379 -1633 1443 627 -1796 725 27 2156 -3625 -1383 -3861 -2370 -1451 1057 1370 -621 -3202 -7043 -6413 -5879 -449 -356 -417 -455 321 415 970 2105 499 851 -596 -745 -171 1385 2021 1527 1721 223 2026 175 -723 -630 -353 1563 3206 3572 2533 643 -1286 -1762 -504 2273 1403 1621 2042 1411 1014 -662 -1982 -3993 -3533 -2288 -2388 -2221 -2569 -2393 -1669 -71 510 1685 1316 1842 1496 222 -353 -2023 -1121 -872 -360 719 1308 457 -918 -1690 -2151 -747 -668 -1718 -1684 -1217 -348 931 1658 1658 839 383 -230 -501 -411 -113 474 1023 700 996 806 1392 739 399 -1449 -754 471 -291 -489 -1141 -1348 -682 -30 222 202 724 1017 625 177 -461 -1413 -208 -215 7 -329 -346 -626 -207 -724 -748 -762 -763 -266 -465 -126 -93 180 -86 43 -200 178 79 -235 96 4 318 -580 -212 -584 -344 -214 168 242 -120 -641 -1418 -1303 -1333 -116 -109 -146 -157 116 154 362 782 189 319 -225 -284 -67 577 904 733 865 118 1080 96 -398 -341 -192 878 1933 2337 1762 450 -864 -1133 -328 1587 1103 1253 1612 1103 824 -503 -1380 -2641 -2332 -1630 -1938 -1857 -2363 -2346 -1722 -77 587 1855 1478 2026 1708 237 -349 -1928 -1081 -914 -420 855 1687 619 -1225 -2100 -2483 -903 -781 -2169 -2248 -1696 -507 1332 2526 2644 1353 596 -336 -738 -584 -163 718 1521 1088 1551 1228 2194 1127 584 -2060 -1040 668 -450 -759 -1871 -2281 -1189 -55 398 378 1382 1958 1202 331 -833 -2663 SS 20241003T131520.4Z 9042.552319 105 1 48.97 2 65.40 120.58 74.23 117.81 0.00 1 0.00 1 0 17 2.414e-02 1.138e-02 1.368e-03 2.717e-04 2.970794e-01 1.420707e-04 3.646806e-03 -6.000000e+00 1.436599e-02 227.15 -2.00 3.51 -2.00 318.31 0.00e+00 1.654670e-03 2.697333e-05 9.106074e-04 -6.000000e+00 6.408281e-04 285.50 -2.00 20.00 -2.00 317.54 0.00e+00 2.386 0.000 302.00 328.00 3 3.1399e-01 3.8203e-04 2.8394e-02 -6.0000e+00 3.5594e-02 2.4931e-03 4.3332e-04 1.5574e-02 -6.0000e+00 3.8478e-02 3.6575e-03 2.8071e-04 7.7603e-03 -6.0000e+00 2.2969e-02 -9.7000e-03 1.4487e-04 2.2900e-03 -6.0000e+00 9.8663e-03 2.5010e-02 3.5733e-05 8.4895e-06 2.5886e-05 -6.0000e+00 7.1027e-04 6.8802e-03 0.0000e+00 12 8 8 10 0 0 9.46 23.25 0.30 0.00688 0.00715 1585 365 1 5 0 30.770 26.62 20.01 23.25 25.69 26.2 1026.13 -1064 -1146 -2364 -6748 -7694 -7630 -5159 -4378 -5557 -8448 -9214 -7157 -4604 -1209 -419 -343 -262 1530 1153 2087 372 441 1165 986 1019 -527 -1885 -2515 -2147 -1553 742 918 183 -4253 -6519 -5450 -4139 -1156 -395 -670 -563 41 573 531 1382 762 408 -97 -632 230 1367 1330 1500 1376 753 1414 359 -230 -463 214 1477 2738 3187 2494 246 -1217 -1300 -619 1941 1511 1163 1560 1142 1168 -406 -1703 -2993 -3515 -2195 -2331 -2332 -2476 -2852 -1539 -218 572 1484 1381 1733 1252 394 -1044 -1797 -780 -702 -205 667 1402 453 -600 -1668 -2150 -938 -541 -1755 -1899 -1049 -742 931 1441 1401 896 454 -209 -627 -369 54 270 1049 489 798 833 1262 687 698 -923 -714 460 -62 -336 -1014 -1276 -521 -10 264 159 767 826 578 -88 -531 -1490 -66 -76 -159 -444 -470 -457 -326 -309 -431 -695 -776 -634 -457 -136 -53 -48 -38 231 183 339 62 74 200 179 195 -105 -371 -476 -390 -285 144 197 42 -1023 -1545 -1293 -1082 -350 -140 -271 -247 19 266 250 646 358 190 -45 -292 108 679 711 772 740 420 802 208 -133 -265 122 877 1741 2183 1797 178 -834 -841 -404 1357 1182 980 1343 973 946 -307 -1181 -1944 -2280 -1523 -1830 -2052 -2381 -2930 -1652 -226 629 1695 1605 1978 1370 439 -1077 -1757 -764 -743 -240 788 1791 605 -788 -2048 -2460 -1138 -629 -2210 -2533 -1452 -1075 1414 2320 2167 1390 732 -315 -885 -500 74 390 1604 787 1291 1319 1922 1011 980 -1254 -942 621 -90 -527 -1672 -2162 -905 -17 467 293 1443 1572 1099 -164 -953 -2611 SS 20241003T132407.5Z 9042.558420 110 1 49.11 2 63.99 122.43 72.83 119.48 0.00 1 0.00 1 0 17 2.193e-02 1.143e-02 1.086e-03 2.449e-04 2.836751e-01 1.278463e-04 3.466305e-03 -6.000000e+00 1.305162e-02 227.15 -2.00 3.51 -2.00 318.13 0.00e+00 1.670646e-03 2.302464e-05 7.962949e-04 -6.000000e+00 5.822260e-04 285.50 -2.00 20.00 -2.00 317.36 0.00e+00 2.267 0.000 302.00 328.00 3 2.7051e-01 3.4148e-04 2.6960e-02 -6.0000e+00 3.2337e-02 4.8697e-03 3.8594e-04 1.4702e-02 -6.0000e+00 3.4959e-02 1.9342e-03 2.4503e-04 7.3096e-03 -6.0000e+00 2.0868e-02 -8.5231e-03 1.2528e-04 2.1745e-03 -6.0000e+00 8.9632e-03 2.9890e-02 2.4533e-05 7.6633e-06 2.4332e-05 -6.0000e+00 6.4534e-04 7.2696e-03 0.0000e+00 12 8 8 10 0 0 9.71 23.22 0.30 0.00727 0.00745 1752 403 1 5 0 27.830 26.62 20.00 23.22 26.21 26.1 1027.61 -132 -659 -2655 -5346 -6749 -6011 -4545 -3004 -4767 -7240 -8559 -6417 -3569 -1117 410 -136 426 1385 1611 2203 651 705 1217 1588 650 -135 -1673 -2059 -2061 -1267 838 1046 431 -4267 -6215 -5411 -3963 -1333 -236 -686 -606 91 397 602 1288 817 266 -45 -691 341 1363 1217 1432 1153 744 1392 467 -283 -356 244 1466 2626 3026 2450 120 -1180 -1433 -651 1904 1449 1178 1566 1189 1107 -340 -1725 -3015 -3447 -2161 -2316 -2339 -2483 -2830 -1501 -300 477 1416 1365 1685 1263 412 -1038 -1744 -773 -656 -239 722 1447 474 -591 -1654 -2157 -966 -519 -1748 -1838 -1043 -709 933 1460 1435 912 509 -204 -549 -408 16 273 1019 487 759 848 1285 696 719 -883 -719 458 -80 -347 -1029 -1292 -496 -27 278 141 767 798 560 -78 -546 -1476 -9 -51 -210 -405 -476 -412 -331 -242 -424 -679 -824 -647 -400 -143 59 -21 70 235 284 400 121 132 232 319 139 -30 -364 -428 -413 -255 178 244 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