File name: Pandora247s1_WhittierCA_20240628_L2Fit_fout2c2d20221229p1-8.txt File generation date: 20240629T080208.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v2d20221229.txt Level 1 file used: Pandora247s1_WhittierCA_20240628_L1_smca1c2d20221229p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20240628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0208 305.1616 305.3025 305.4433 305.5842 305.7250 305.8658 306.0066 306.1474 306.2881 306.4289 306.5696 306.7104 306.8511 306.9918 307.1325 307.2732 307.4139 307.5546 307.6952 307.8359 307.9765 308.1171 308.2577 308.3983 308.5389 308.6795 308.8201 308.9607 309.1012 309.2417 309.3823 309.5228 309.6633 309.8038 309.9443 310.0847 310.2252 310.3656 310.5061 310.6465 310.7869 310.9273 311.0677 311.2081 311.3484 311.4888 311.6291 311.7695 311.9098 312.0501 312.1904 312.3307 312.4710 312.6112 312.7515 312.8917 313.0320 313.1722 313.3124 313.4526 313.5928 313.7330 313.8731 314.0133 314.1534 314.2936 314.4337 314.5738 314.7139 314.8540 314.9941 315.1341 315.2742 315.4142 315.5542 315.6943 315.8343 315.9743 316.1142 316.2542 316.3942 316.5341 316.6740 316.8140 316.9539 317.0938 317.2337 317.3736 317.5134 317.6533 317.7931 317.9330 318.0728 318.2126 318.3524 318.4922 318.6320 318.7717 318.9115 319.0512 319.1910 319.3307 319.4704 319.6101 319.7498 319.8894 320.0291 320.1687 320.3084 320.4480 320.5876 320.7272 320.8668 321.0064 321.1460 321.2855 321.4251 321.5646 321.7041 321.8436 321.9831 322.1226 322.2621 322.4016 322.5410 322.6804 322.8199 322.9593 323.0987 323.2381 323.3775 323.5168 323.6562 323.7955 323.9349 324.0742 324.2135 324.3528 324.4921 324.6314 324.7706 324.9099 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240628T144847.2Z 8945.617213 228 1 54.58 2 66.69 76.85 37.82 210.49 0.00 1 0.00 1 0 17 1.158e-02 6.084e-03 1.534e-03 4.330e-04 3.358684e-01 2.312434e-04 3.791097e-03 -6.000000e+00 7.101867e-03 232.09 -2.00 3.36 -2.00 317.43 0.00e+00 4.849680e-04 3.556089e-05 1.820678e-04 -6.000000e+00 3.213870e-04 291.03 -2.00 20.00 -2.00 316.55 0.00e+00 2.507 0.000 302.00 328.00 3 2.0816e+00 6.1643e-04 2.9983e-02 -6.0000e+00 1.7761e-02 -2.8985e-02 6.9173e-04 1.6810e-02 -6.0000e+00 1.9123e-02 -1.0349e-02 4.1338e-04 8.1073e-03 -6.0000e+00 1.1421e-02 2.2889e-03 2.0226e-04 2.2219e-03 -6.0000e+00 4.8111e-03 3.7380e-03 8.2138e-05 1.3463e-05 2.7538e-05 -6.0000e+00 3.5939e-04 -4.4733e-03 1.5744e-04 10 0 0 10 0 0 99.99 26.05 0.33 -0.00447 -0.00386 836 83 1 5 0 65.274 33.75 20.00 26.05 27.99 35.2 995.63 -1209 -2755 -2028 -3108 -5911 -3244 -1837 -1851 -1792 -2129 -4135 -2727 -627 -1003 -227 175 -1128 165 447 651 865 396 682 935 85 247 -359 -1315 -733 45 988 954 683 9 -2845 -2242 -1262 -1316 89 -147 -938 -960 -277 -921 -326 386 -258 -287 -100 -137 810 1073 748 1353 757 750 1150 600 315 605 992 1515 1676 1350 762 -613 57 -66 524 1588 348 72 41 7 175 -329 -125 -401 -529 -54 -1236 -1444 -1771 -2204 -1169 -836 -427 7 24 215 202 582 234 362 778 543 288 355 215 -530 -543 -805 -736 131 109 -1233 -887 -660 -547 301 347 250 157 259 186 256 595 489 408 258 -160 -75 198 411 303 746 122 513 1023 335 137 -283 -372 -84 128 -75 -251 151 126 -230 -126 -258 -696 -102 -267 -206 -314 -576 -292 -167 -185 -200 -257 -479 -325 -81 -151 -39 34 -242 37 97 147 200 93 164 235 23 70 -103 -370 -197 12 268 284 223 3 -925 -712 -418 -499 37 -72 -483 -532 -149 -509 -181 213 -143 -157 -55 -76 463 658 465 887 522 535 789 417 218 413 688 1111 1263 1096 641 -507 44 -50 411 1363 317 67 39 6 158 -273 -99 -320 -410 -46 -1144 -1424 -1819 -2315 -1293 -945 -490 9 29 252 232 644 251 373 828 607 346 436 275 -695 -709 -1016 -872 153 135 -1590 -1156 -903 -762 429 526 379 236 383 265 357 808 684 583 378 -244 -114 293 607 428 1038 164 679 1419 486 206 -430 -583 -132 211 -127 -429 263 221 -400 -219 -429 -1170 SS 20240628T145413.5Z 8945.620990 231 1 54.66 2 65.59 77.50 38.38 212.46 0.00 1 0.00 1 0 17 1.212e-02 6.114e-03 2.905e-03 8.309e-04 3.227325e-01 4.440790e-04 3.644061e-03 -6.000000e+00 7.432479e-03 232.09 -2.00 3.36 -2.00 317.37 0.00e+00 4.388738e-04 6.761910e-05 1.806646e-04 -6.000000e+00 3.363361e-04 291.03 -2.00 20.00 -2.00 316.50 0.00e+00 2.403 0.000 302.00 328.00 3 3.4499e+00 1.1828e-03 2.8763e-02 -6.0000e+00 1.8588e-02 -1.6426e-02 1.3259e-03 1.6155e-02 -6.0000e+00 2.0013e-02 -1.1979e-02 7.9221e-04 7.7941e-03 -6.0000e+00 1.1953e-02 2.7399e-03 3.8771e-04 2.1343e-03 -6.0000e+00 5.0353e-03 1.0646e-03 9.4528e-05 2.6002e-05 2.6602e-05 -6.0000e+00 3.7609e-04 -4.6875e-03 1.6309e-04 10 0 0 10 0 0 99.99 26.05 0.29 -0.00469 -0.00398 259 26 1 5 0 211.006 33.75 20.00 26.05 28.17 35.2 996.13 -776 -2974 -1149 -2985 -5760 -1608 -2760 -2117 417 -2170 -4701 -3491 -1090 -2166 -1036 740 -2089 181 1222 895 1045 1216 552 1052 791 -83 -618 -1492 -870 740 1272 1049 891 -54 -3036 -2642 -724 -1455 227 56 -741 -820 -310 -1511 -372 206 -187 -227 -93 -233 595 1008 875 1231 866 743 925 944 344 740 982 1692 1668 1064 829 -623 -198 -68 492 1609 96 132 66 4 263 -202 -262 -498 -486 -285 -1197 -1471 -1808 -2117 -1120 -625 -306 95 64 136 274 588 139 332 658 658 222 426 122 -495 -571 -655 -763 63 79 -1297 -838 -475 -620 278 388 259 98 305 80 287 539 573 508 275 -175 -86 256 405 199 782 46 454 1049 276 103 -326 -346 -170 216 -161 -215 179 127 -285 -88 -188 -706 -66 -293 -117 -304 -564 -143 -253 -212 45 -261 -599 -457 -154 -324 -177 140 -440 39 276 212 254 299 139 276 221 -22 -170 -401 -242 199 354 293 272 -17 -1000 -851 -241 -557 94 27 -378 -449 -176 -886 -217 120 -108 -130 -53 -134 354 599 558 829 573 508 645 663 240 512 690 1253 1261 868 696 -514 -153 -54 382 1367 86 126 63 4 234 -174 -206 -394 -394 -238 -1079 -1403 -1880 -2231 -1244 -703 -364 112 76 165 314 651 143 344 704 731 263 533 158 -654 -725 -808 -927 75 96 -1704 -1103 -655 -866 411 585 403 150 446 114 399 730 799 719 398 -263 -129 373 593 279 1086 62 600 1445 396 151 -501 -548 -269 358 -272 -363 309 222 -491 -151 -312 -1146 SS 20240628T150133.2Z 8945.626079 236 1 11.46 2 64.10 78.38 39.17 215.03 0.00 1 0.00 1 0 17 2.192e-02 8.399e-03 1.690e-02 4.794e-03 3.035609e-01 2.560552e-03 3.382989e-03 -6.000000e+00 1.346806e-02 232.09 -2.00 3.36 -2.00 317.45 0.00e+00 4.427232e-04 3.992984e-04 1.521372e-04 -6.000000e+00 6.096696e-04 291.03 -2.00 20.00 -2.00 316.57 0.00e+00 2.276 0.000 302.00 328.00 3 5.1526e+00 6.8217e-03 2.7132e-02 -6.0000e+00 3.3685e-02 -2.6910e-03 7.6608e-03 1.5109e-02 -6.0000e+00 3.6267e-02 2.6693e-04 4.6103e-03 7.2939e-03 -6.0000e+00 2.1643e-02 -5.3889e-03 2.2659e-03 2.0522e-03 -6.0000e+00 9.1765e-03 2.2463e-04 1.9328e-03 1.5072e-04 2.4790e-05 -6.0000e+00 6.8398e-04 -7.7568e-03 4.5192e-04 12 9 1 12 9 1 99.28 26.05 0.36 -0.00776 0.00677 3 2 1 5 0 2864.160 33.75 20.00 26.05 28.48 35.2 996.22 900000 -2574 3424 -1377 -6873 290 13729 -2916 2346 -5198 -4811 -2408 -2533 -4806 2882 -791 -5931 3165 2618 -2927 742 1977 2461 -682 3161 3911 -2166 -3405 -779 5702 67 2006 178 -1968 -602 -4929 1394 -1838 917 1512 473 -390 -988 -4931 -355 1193 -1993 -1281 -398 -121 1688 1821 951 822 616 205 1687 1371 537 815 39 1334 1527 388 986 250 -406 -462 1132 2100 -1046 192 881 -62 340 -574 -905 -852 -594 -570 -654 -921 -1030 -2471 -1325 -152 -714 -208 340 1134 479 1449 -269 -191 1169 1656 -173 -213 42 21 -228 -1192 -1154 -445 378 -1258 -1239 -642 -302 231 -67 1342 49 385 -344 33 -177 640 172 76 -367 573 -148 908 180 248 181 863 1034 -331 157 -28 -326 -734 377 412 -159 132 474 -527 93 -109 -999 900000 -248 326 -135 -665 25 1040 -286 243 -624 -594 -300 -347 -773 494 -143 -1222 628 547 -673 169 451 568 -170 802 1030 -612 -945 -201 1347 17 552 54 -641 -191 -1604 447 -695 367 706 231 -206 -545 -2884 -199 661 -1132 -711 -217 -66 945 1088 613 521 408 141 1164 953 373 560 28 985 1219 313 810 200 -328 -361 904 1713 -971 175 809 -56 308 -480 -739 -656 -464 -457 -592 -870 -1056 -2570 -1449 -176 -831 -250 411 1329 564 1557 -288 -196 1219 1764 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